'Mr. and Mrs. Smith' Red Carpet Flashback! Photos from the ‘Brangelina’ Movie’s Premiere

When Brad Pitt and Angelina Jolie attended the premiere of their action-romance ‘Mr. and Mrs. Smith’ in Los Angeles on June 7, 2005, they hadn’t yet confirmed their relationship — and wouldn’t, until Jolie announced her pregnancy six months later. Pitt and his then-estranged-wife Jennifer Aniston were in the midst of divorce proceedings, and he and his co-star were laying low. But looking at the way those two glowed for the cameras, it’s clear that love was in the air. (Read more about the backstory here.) As news broke on Sept. 20, 2016, of Jolie filing for divorce from Pitt, look back at the red-carpet event for the movie that brought them together and marked the start of a dozen years of “Brangelina” to come. Also see our photo histories of Angelina Jolie and Brad Pitt on the red carpet.