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Jennifer Aniston

Best blonde in black: Jennifer Aniston. OK, so yes, a little awkward to throw Brad Pitt's ex in the mix — especially since Jennifer Aniston hasn't even attended the Golden Globes ceremonies in a couple of years. Still, people rave — and search online — for that one-shoulder, high-slit Valentino Couture gown she wore in 2010, with lots and lots of bronzer. She also plunged into a Valentino in 2004 (and it plunged for her), and she pulled off a tuxedo pantsuit — no shirt — in 2002.