The sisters and grown-ish stars are also nominated in the best group category.
Chloe x Halle dropped their second LP, Ungodly Hour, in June, and were named the new faces of Fendi's Peekaboo bag the following month. In September, they kicked off the 2020 NFL season with a powerful rendition of the national anthem.
Previously announced performer Justin Bieber will also be taking the stage at the People's Choice Awards, airing live on Sunday from the Barker Hangar in Santa Monica, California.
Jon Kopaloff/Getty Images Justin Bieber
E! also announced on Tuesday that the following celebrities will take the stage as presenters at this year's show: Addison Rae, Alison Brie, Armie Hammer, Bebe Rexha, Christina Hendricks, Jameela Jamil, Kathryn Hahn, Machine Gun Kelly, Sofia Carson, Tiffany Haddish and Tyler, the Creator.
"idk... maybe hosting @peopleschoice?!?!? #PCAs," 28-year-old singer replied.
The 2020 E! People's Choice Awards will broadcast live on Sunday at 9 p.m. ET on Bravo, E!, SYFY and USA.