On the set of the spy-movie, Mr. and Mrs. Smith (which is getting a reboot), Angelina Jolie and Brad Pitt met. In an interview with Vogue (via People) in 2006, Jolie confirmed that they developed feelings for each other while filming, but didn’t start thinking of getting together instantly. "It took until, really, the end of the shoot for us, I think, to realize that it might mean something more than we’d earlier allowed ourselves to believe."

Jolie and Pitt married in 2014, but later filed for divorce.