11 TV And Movie Couples Whose Chemistry Was So Good Because The Actors Literally Had Crushes On Each Other

One of the most important parts of a TV show or movie is making sure that the chemistry between characters — especially love interests — is off the charts.

Fox

With casting directors making sure to pick actors with good chemistry, and those actors canoodling on screen for months on end...it makes sense that some of them developed a real attraction to each other.

Zendaya resting her head on Tom Holland's shoulder labeled "now dating after starring in "Spider-Man" films together"

Lookin' at you, Tom and Zendaya.

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Here are 11 different TV and movie couples where the actors have actually admitted to feeling attraction for their costar while filming was going on!

1.Good Will Hunting launched the careers of not only Ben Affleck and Matt Damon, but also Minnie Driver, who played Damon's character's girlfriend, Skylar.

Skylar and Will about to kiss in the film
Miramax / courtesy Everett Collection

Damon and Driver were both nominated for Oscars for their performances. The two were extremely believable as a couple and performed in multiple intense scenes together...and quickly became a couple IRL.

Skyler: ""I want to hear you say that you don't love me. Because if you say that, then I won't call you. And I won't be in your life" Will: "I don't love you"

The amount of times I saw this scene performed in acting class...

Miramax Films

In fact, Driver said that she was “completely in love with Matt” by the time she filmed her scenes with him. They soon began dating, with Damon telling David Letterman that Driver "pretty much rocked my world.”

Driver and Damon on a red carpet

However, a month later, he broke up with her by announcing on Oprah that he was single.

Steve Granitz Archive / WireImage via Getty Images

2.Back in the '90s, the big "will they/won't they" TV couple everyone was talking about was Ross and Rachel from Friends.

  Warner Bros. / Courtesy: Everett Collection
Warner Bros. / Courtesy: Everett Collection

The two had incredible chemistry and ended up in a relationship various times during the show...leading fans to wonder if the actors, Jennifer Aniston and David Schwimmer, had similar chemistry.

Ross coming to the cafe and kissing Rachel
NBC

Well, it took until 2021, but the two finally admitted during the Friends reunion special that they had a crush on each other during filming of the show. Unfortunately, as they were always dating other people, nothing came of it.

David said he had a big crush on Jen in season 1, and Jen says it was reciprocated. David says it was like 2 ships passing because one of them was always in a relationship so they never got together
HBO Max

3.Sandra Bullock and Keanu Reeves first met when they starred in the action thriller Speed in 1994.

Sandra and Keanu in the film
20th Century Fox / Courtesy Everett Collection.

The actors had such great chemistry that they also starred in the romantic film The Lake House together and struck up a lifelong friendship filled with romantic gestures — like Sandra telling Keanu she'd never had champagne and truffles, and a few days later he showed up at her house on his motorcycle with champagne and truffles.

Sandra and Keanu on a red carpet
Jeff Kravitz / FilmMagic, Inc via Getty Images

Though the two never went on a date, Sandra told Ellen DeGeneres in 2018 that she'd had a crush on Keanu, and then Keanu told Ellen the same a year later.

Ellen shows Keanu a clip of Sandra talking about her crush on him, asking if he knew — he says no and that he also had a crush on her. Ellen says the chemistry was real then

Bullock has said of their friendship over a relationship: "We just get to grow up together on parallel roads and tip our hats and meet for a dinner and try to work together. And the longer time goes on, the more in awe I am of the human being."

ABC

4.Angelina Jolie and Brad Pitt were one of Hollywood's biggest it couples for a decade. Where did they meet? On the set of the 2005 romantic thriller Mr. & Mrs. Smith.

Brad and Angelina in the film
20th Century Fox / Courtesy Everett Collection

Even though Pitt was still married to Jennifer Aniston, reports began circulating that their palpable "onscreen chemistry was turning into something more intimate offscreen." The rumors were denied, but then Pitt and Aniston announced they were separating while reshoots were still going on for the film, and Brangelina was born.

Brad and Angelina at a premiere
Lester Cohen / WireImage via Getty Images

Jolie would later say, "Because of the film, we ended up being brought together to do all these crazy things, and I think we found this strange friendship and partnership that kind of just suddenly happened. I think a few months in I realized, 'God, I can't wait to get to work.' … Anything we had to do with each other, we just found a lot of joy in it together and a lot of real teamwork. We just became kind of a pair."

The two married in 2014 after years of dating and raising a family together, and they filed for divorce in 2016.

The two married in 2014 after years of dating and raising a family together, and they filed for divorce in 2016.

James Devaney / WireImage via Getty Images

5.Another Hollywood it couple of the naughts was Ben Affleck and Jennifer Garner.

Ben and Jen at a red carpet
Jeff Kravitz / FilmMagic via Getty Images

They met on the set of Pearl Harbor, but wouldn't play love interests until Daredevil. The film was critically panned, but I have to say, the scenes between Ben and Jen were pretty steamy.

Ben and Jen kissing in daredevil
20th Century Fox / Courtesy Everett Collection

While Affleck and Garner didn't publicly get together until 2004, Affleck would later say that Daredevil was where they fell in love...even though Jennifer was married and Ben was dating Jennifer Lopez. Even if nothing happened between them back then, their chemistry was clearly real.

Jennifer and Ben at a game labeled "first time photographed as a couple"
Allen Kee / WireImage via Getty Images

6.Mandy Moore transitioned from a singing career to a movie career when she appeared alongside Shane West in the romantic teen film A Walk to Remember. While certainly not a critical darling, the film was much-loved by teen audiences, mostly because of its central relationship and the performances of the actors.

  Warner Brothers / courtesy Everett Collection
Warner Brothers / courtesy Everett Collection

West recently admitted, "There was chemistry. I think we [Mandy and I] both had a little bit of a crush, but then we were just there for each other in the most honest and purest of ways. That sounds incredibly corny, but is true and rare."

Shane West and Mandy Moore at the premiere of "A Walk To Remember"
Kevin Winter / Getty Images

7.One of the most memorable parts of ER was the steamy relationship between Carol and Doug, played by Julianna Margulies and George Clooney.

Carol and Doug hugging
NBC / Courtesy: Everett Collection

Speaking about their chemistry, Margulies said, "that can't happen if you don't have a crush on each other. And with George and me, it was so organic."

Margulies and Clooney at the golden globes
S. Granitz / WireImage via Getty Images

However, the two never entered into a relationship. Margulies said that instead, he became her mentor and helped her feel safe on set. They also became lifelong friends. "He and I always joke that thank god nothing ever happened, because now we can remain friends for the rest of our lives," Margulies said.

Julianne and George in 2013
Trae Patton / NBC / NBCUniversal via Getty Images)

8.Hugh Jackman's first job out of drama school was on the Australian miniseries Correlli. In the series, Jackman played Kevin, an inmate suffering from brain damage, while Deborra-Lee Furness played his psychologist. "There was a chemistry. And every time we had a scene together, it was unbelievable. ... Professionally, I've never had anything quite like that again," Jackman said of filming with Furness.

Kevin asks Louisa where they stand, then kisses her after she acts surprised/confused
ABC TV

Jackman had a crush on Furness from the start, but took weeks to reveal his feelings, as he thought it was "unprofessional and embarrassing" to hold a flame for his "leading lady." He tried ignoring her for a week — when she asked him why, he told her the truth, and she replied that she had a crush on him too.

the two at the 2002 Tonys

They began dating, and were married in 1996.

Scott Gries/ImageDirect via Getty Images

9.I know reactions are mixed as to the quality of the Twilight films, but Robert Pattinson and Kristen Stewart, at least to me, were the perfect Edward and Bella.

Edward to Bella: "I just want to try one thing. Just stay very still. Don't move" Then he kisses Bella
Summit Entertainment

Robert actually had a crush on Kristen even before filming, saying "I knew before I met her that we had chemistry," which Kristen agreed with. The two ended up dating for almost four years.

Robert and Kristen on a red carpet

They broke up in 2013.

Mark Makela/Corbis via Getty Images

10.Maybe it wasn't as ~steamy~ of a fictional relationship, but Troy and Gabriella in High School Musical were definitely every 2000s kid's dream couple.

Troy and Gabriella singing karaoke
Fred Hayes / Disney Channel / Courtesy Everett Collection

They were basically the epitome of young love, and their sweet, innocent chemistry carried three films — during which the actors, Zac Efron and Vanessa Hudgens, dated in real life as well.

Gabriella asks Troy if he remembers how in kindergarten you could make best friends in seconds because you could just be yourself, and says singing with him felt like that — troy says he never thought about singing before gabriella
Disney Channel

Hudgens later said she remembered having such a crush on him when they met, and Zac has said the same, saying they clicked right away.

Zac and Vanessa on a red carpet
Jon Kopaloff / FilmMagic via Getty Images

11.And finally, Kate Winslet and Guy Pearce stole our hearts on Mare of Easttown, but they had actually worked together before — on the 2011 miniseries Mildred Pierce, where they played love interests.

Monte kissing Mildred's neck in the show
HBO

When they first met on set of the miniseries, Winslet admitted to Guy that she'd had a childhood crush on him after seeing him in Neighbours. "Look, I've been in love with you since I was 11. And we share the same birthday, which I've also known since I was 11 years old," she told him.

Pearce in Neighbours labeled "Kate Winslet's first crush"
Seven Network

For his part, Pearce (who was married at the time) was a little nervous to work with Kate, saying, "She's someone I've had quite a crush on for many years. So suddenly there we are, naked together. It's a weird job." Their chemistry was clear in the show, for which they both won Emmys.

Guy and Kate on a red carpet
Gregorio T. Binuya/Everett Collection

Did any of these surprise you? Are there any examples of the opposite — costars playing love interests who hated each other? Let us know in the comments!